Department of Research & Development, RWO GmbH-Marine Water Technology, Veolia Water Solutions & Technologies, Thalenhorststrasse 15A, 28307, Bremen, Germany.
Water Sci Technol. 2009;60(9):2227-34. doi: 10.2166/wst.2009.676.
A full-scale 500 m(3)/h ballast water treatment system was tested according to the landbased type approval procedure of the International Maritime Organization (IMO). The system consists of disc filters followed by the advanced EctoSys electrolysis as an integral part for disinfection. The test water quality exceeded by far the minimum requirements for type approval testing. Due to the properties of the special electrodes used together with the striking disinfection effect, the disinfectants assumed to be produced inline by the EctoSys cell in river water were hydroxyl radicals, while in brackish water additionally chlorine and consequently the more stable bromine were formed. In river water, no residual oxidants could be detected in accordance with the assumed production of not responding, highly-reactive and short-living hydroxyl radicals. Accordingly, disinfection byproduct (DBP) formation was very low and close to the limit of quantification in river water. While in brackish water, initial residual oxidant concentrations were maximum 2 mg/L as chlorine and mostly brominated DBP (especially bromoform and bromate) were found. Overall considering this worst case test approach, the DBP concentrations of the treated effluents were below or in the range of the WHO Drinking Water Guideline values and therefore evaluated as acceptable for discharge to the environment. The stringent discharge standard by IMO concerning viable organisms was fully met in river and brackish water, proving the disinfection efficiency of the EctoSys electrolysis against smaller plankton and bacteria.
按照国际海事组织(IMO)的陆基型式认可程序,对一个 500 m³/h 的海水处理系统进行了全面测试。该系统由圆盘过滤器和先进的 EctoSys 电解槽组成,后者是消毒的一个组成部分。测试水质远远超过了型式认可测试的最低要求。由于使用了特殊电极的特性以及显著的消毒效果,EctoSys 电解槽在线产生的消毒剂被认为是在河水中产生的羟基自由基,而在微咸水中则形成了氯,随后形成了更稳定的溴。在河水中,由于假设产生的非响应、高反应性和短寿命的羟基自由基,因此未检测到残留氧化剂。因此,消毒副产物(DBP)的形成非常低,接近于河水中的定量下限。而在微咸水中,初始残留氧化剂浓度最高为 2mg/L 的氯,并且主要发现了溴化 DBP(尤其是三溴甲烷和溴酸盐)。总体而言,考虑到这种最坏情况的测试方法,处理后的废水中的 DBP 浓度低于或在世界卫生组织饮用水指南值范围内,因此被评估为可排放到环境中。IMO 对活生物体的严格排放标准在河水和微咸水中都得到了完全满足,证明了 EctoSys 电解槽对较小的浮游生物和细菌的消毒效率。