Order versus disorder in chiral tetrathiafulvalene-oxazoline radical-cation salts: structural and theoretical investigations and physical properties.

Electrocrystallization experiments with the chiral ethylenedithio-tetrathiafulvalene-methyl-oxazoline (EDT-TTF-OX) donors (R)-, (S)-, and (rac)-1 have provided two series of mixed-valence salts with the PF(6) (-) and Au(CN)(2) anions. Within each series the cell parameters are the same for the three R, S, and rac compounds, except for the space group, which is centrosymmetric triclinic P$\bar 1$ for the racemic forms and noncentrosymmetric P1 for the enantiopure salts. In the racemic salt (rac)-1PF(6) the two enantiomers crystallize disordered on the same crystallographic site with a site occupational factor of 0.6:0.4, whereas this type of disorder is not possible in the enantiopure salts. Both s-cis and s-trans conformations, when taking into account the mutual orientation of the TTF and oxazoline moieties, are present in this first series. In sharp contrast, in the series of salts 1[Au(CN)(2)], only the s-trans conformation is observed with no structural disorder. Theoretical calculations at the DFT level of theory revealed a very small energy difference between the two stable planar s-cis and s-trans conformations, which are both energy minima in either neutral or oxidized states. Single-crystal conductivity measurements showed metallic-like behavior for all the salts down to 220-250 K with a smooth increase in resistivity at lower temperatures. The conductivity at room temperature is 5 S cm(-1) for (rac)-1PF(6), in which disorder was observed, whereas for (R)-1PF(6) and (S)-1PF(6) the average value is around 100 S cm(-1). In the second series of salts the conductivity at room temperature is 125-130 S cm(-1) for (rac)-1[Au(CN)(2)] and (R)-1[Au(CN)(2)]. Extended Hückel band structure calculations revealed identical features for the three salts of the 1[Au(CN)(2)] series and are consistent with the electronic structures of quasi-one-dimensional conductors.