基于 Borylene 的 Pt-炔基配合物的功能化，通过 [(OC)(5)Cr=BN(SiMe(3))(2)] 的光化学 Borylene 转移实现。
Borylene-based functionalization of Pt-alkynyl complexes by photochemical borylene transfer from [(OC)(5)Cr=BN(SiMe(3))(2)].
机构信息
Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, D-97074 Würzburg, Germany.
出版信息
Chem Commun (Camb). 2009 Dec 7(45):6979-81. doi: 10.1039/b915926f. Epub 2009 Oct 15.
DOI:10.1039/b915926f
PMID:19904367
Abstract
Photochemical borylene transfer from [(OC)(5)Cr=BN(SiMe(3))(2)] to the platinum sigma-alkynyl complex [Cl(PMe(3))(2)Pt-C[triple bond]CPh] gave facile access to the first transition metal-borirene complex. The title compound has been fully characterized in solution and by X-ray crystallography.
摘要
光致硼烯从[(OC)(5)Cr=BN(SiMe(3))(2)]转移到铂西格玛-炔基配合物[Cl(PMe(3))(2)Pt-C[三键]CPh]，为获得第一个过渡金属-硼烯配合物提供了便利途径。标题化合物已在溶液中和通过 X 射线晶体学得到充分表征。
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