National Institute for Agro-Environmental Science, Tsukuba, Ibaraki, Japan.
J Agric Food Chem. 2009 Dec 9;57(23):11261-6. doi: 10.1021/jf902573k.
To prevent the distribution of cucumbers with dieldrin contamination exceeding the limit set by the Japanese Food Sanitation Law, the extraction solvent for dieldrin-contaminated soil was selected prior to cultivation so that the dieldrin residue level in cucumber could be predicted. The exhaustive extraction from soil could not explain the dieldrin uptake by cucumber plants. However, significant correlation (R(2) = 0.966, P < 0.001) was observed between dieldrin concentrations in cucumber and dieldrin concentrations extracted with 50% (v/v) methanol-water solution from soils. This was a result of the phytoavailability of dieldrin to the cucumber plants. The extractability of soil dieldrin with the methanol-water solution decreased as the organic carbon content in the soils increased. This suggested that a 50% (v/v) methanol-water solution is the optimal solution for predicting dieldrin concentrations in cucumbers by soil analysis.
为防止敌敌畏残留量超过日本食品卫生法规定限量的黄瓜上市,在种植前选择了用于提取受敌敌畏污染土壤的溶剂,以便预测黄瓜中的敌敌畏残留量。从土壤中进行的彻底提取并不能解释黄瓜植株对敌敌畏的吸收。然而,在黄瓜中检测到的敌敌畏浓度与从土壤中用 50%(v/v)甲醇-水溶液提取的敌敌畏浓度之间存在显著相关性(R(2)=0.966,P <0.001)。这是由于黄瓜植株对敌敌畏的植物可利用性。随着土壤中有机碳含量的增加,用甲醇-水溶液提取土壤中敌敌畏的可提取性降低。这表明 50%(v/v)甲醇-水溶液是通过土壤分析预测黄瓜中敌敌畏浓度的最佳溶液。