Oliveira Tiago J, Stilck Jürgen F, Serra Pablo
Instituto de Física, Universidade Federal Fluminense, Av Litorânea s/n, 24210-346 Niterói, RJ, Brazil.
Phys Rev E Stat Nonlin Soft Matter Phys. 2009 Oct;80(4 Pt 1):041804. doi: 10.1103/PhysRevE.80.041804. Epub 2009 Oct 14.
We solve a model of polymers represented by self-avoiding walks on a lattice, which may visit the same site up to three times in the grand-canonical formalism on the Bethe lattice. This may be a model for the collapse transition of polymers where only interactions between monomers at the same site are considered. The phase diagram of the model is very rich, displaying coexistence and critical surfaces, critical, critical end point, and tricritical lines, as well as a multicritical point. From the grand-canonical results, we present an argument to obtain the properties of the model in the canonical ensemble, and compare our results with simulations in the literature. We do actually find extended and collapsed phases, but the transition between them, composed by a line of critical end points and a line of tricritical points, separated by the multicritical point, is always continuous. This result is at variance with the simulations for the model, which suggest that part of the line should be a discontinuous transition. Finally, we discuss the connection of the present model with the standard model for the collapse of polymers (self-avoiding, self-attracting walks), where the transition between the extended and collapsed phases is a tricritical point.
我们求解了一个由晶格上的自回避行走表示的聚合物模型,在贝塞晶格的巨正则形式中,该聚合物最多可三次访问同一位置。这可能是一个仅考虑同一位置单体间相互作用的聚合物塌缩转变模型。该模型的相图非常丰富,展示了共存和临界面、临界点、临界端点、三临界点以及多临界点。基于巨正则结果,我们给出了一个在正则系综中获取模型性质的论证,并将我们的结果与文献中的模拟结果进行比较。我们确实发现了伸展相和塌缩相,但它们之间的转变,由一条临界端点线和一条三临界点线组成,被多临界点隔开,始终是连续的。这一结果与该模型的模拟结果不同,模拟结果表明这条线的一部分应该是不连续转变。最后,我们讨论了当前模型与聚合物塌缩的标准模型(自回避、自吸引行走)的联系,在该标准模型中,伸展相和塌缩相之间的转变是一个三临界点。