Ryu G Y, Lee S G, Lim S H, Kim G Y, Kim Y K, Shin D M
Department of Electric Information and Control Engineering, Hongik University, Seoul 121-791, Korea.
J Nanosci Nanotechnol. 2009 Dec;9(12):6983-7. doi: 10.1166/jnn.2009.1655.
A red fluorescent material (2E,2'E)-3,3'-[4,4"-bis(dimethylamino)-1,1': 4',1 "-terphenyl-2',5'-diyl]bis[2-(2-thienyl)acrylonitrile] (ABCV-Th) was synthesized for use in organic light emitting diodes (OLEDs) as the host emissive material. It has been reported some green and blue host emissive materials used in OLEDs revealed high device performance but, owing to concentration quenching, comparable red light emitting materials are still rare in OLEDs application. Non-doped organic light emitting diodes, with the structure of ITO/NPB/ABCV-Th (30 nm and 50 nm)/BCP/Alq3/Liq/Al were fabricated using ABCV-Th as the host emitter. The peak wavelength and full width at half maximum (FWHM) of electroluminescence (EL) were 629.5 nm and 68.5 nm, respectively. The maximum brightness and turn on voltage of the device were measured to be 1330 cd/m2 at 14.6 V and 3.4 V, respectively. The device exhibited authentic red emission (Commission Internationale De L'Eclairage (CIE(xy)) = 0.65, 0.34) which is almost close to the standard red (CIE(xy) = 0.67, 0.33) demanded by the national television system committee (NTSC).
一种红色荧光材料(2E,2'E)-3,3'-[4,4"-双(二甲基氨基)-1,1':4',1"-三联苯-2',5'-二基]双2-(2-噻吩基)丙烯腈被合成出来用于有机发光二极管(OLED)作为主体发光材料。据报道,一些用于OLED的绿色和蓝色主体发光材料显示出高器件性能,但是,由于浓度猝灭,在OLED应用中可与之媲美的红色发光材料仍然很少见。使用ABCV-Th作为主体发射体,制备了结构为ITO/NPB/ABCV-Th(30纳米和50纳米)/BCP/Alq3/Liq/Al的非掺杂有机发光二极管。电致发光(EL)的峰值波长和半高宽(FWHM)分别为629.5纳米和68.5纳米。该器件的最大亮度和开启电压分别在14.6伏时测得为1330坎德拉每平方米和在3.4伏时测得为开启电压。该器件呈现出纯正的红色发射(国际照明委员会(CIE(xy))=0.65,0.34),这几乎接近国家电视系统委员会(NTSC)要求的标准红色(CIE(xy)=0.67,0.33)。