Département de Chimie, Pavillon Roger Gaudry, Université de Montréal, CP6128, Québec, Canada H3C 3J7.
J Org Chem. 2009 Dec 18;74(24):9497-500. doi: 10.1021/jo901965t.
The electrochromic and photophysical behaviors of unsymmetric bipyrroles were observed as intense color changes of the oxidized products relative to the neutral form. The color of the oxidized form and the oxidation potential were both tunable contingent on electronic group and substitution.
观察到不对称双吡咯的电致变色和光物理行为,相对于中性形式,氧化产物表现出强烈的颜色变化。氧化形式的颜色和氧化电位都可以通过电子基团和取代基进行调节。