从 2'-羰基-C-糖呋喃糖苷合成 N-取代亚氨基糖。
Synthesis of N-substituted iminosugars from 2'-carbonyl-C-glycofuranosides.
机构信息
Natural Products Research Center, Chengdu Institute of Biology, Chinese Academy of Sciences, Chengdu 610041, China.
出版信息
Carbohydr Res. 2009 Dec 14;344(18):2454-60. doi: 10.1016/j.carres.2009.08.024. Epub 2009 Sep 2.
PMID:19917320
Abstract
Under basic conditions 2'-carbonyl 5-N-substituted-C-glycofuranosides undergo a tandem beta-elimination and intramolecular hetero-Michael addition to form N-substituted iminosugar derivatives in good to excellent yields.
摘要
在基本条件下，2'-羰基 5-N-取代-C-糖呋喃糖苷经历串联β消除和分子内杂迈克尔加成，以良好至优异的收率形成 N-取代亚氨基糖衍生物。
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