Research Center of Green Chirality, Zhejiang University of Technology, Hangzhou 310032, China.
J Chromatogr B Analyt Technol Biomed Life Sci. 2010 May 15;878(17-18):1264-76. doi: 10.1016/j.jchromb.2009.10.031. Epub 2009 Nov 5.
In recent years, the continuous evolution of the field of stereochemistry has produced a heightened awareness of the applications of pure enantiomers of agrochemicals. This review describes reports of the enantiomeric separation of commercial organophosphorus pesticides (OPs) and the applications of these methods to research on the enantioselectivity of the toxicity and environmental fate of these compounds. Chiral OPs can be analysed by high-performance liquid chromatography (HPLC), gas chromatography (GC), and capillary electrophoresis (CE). These different separation techniques for OP enantiomers are briefly discussed, and their applications are presented.
近年来，立体化学领域的不断发展，使人们更加关注农用化学品纯对映体的应用。本综述描述了商业有机磷农药（OPs）对映体分离的报道，以及这些方法在研究这些化合物毒性和环境命运的对映选择性方面的应用。手性 OPs 可以通过高效液相色谱（HPLC）、气相色谱（GC）和毛细管电泳（CE）进行分析。简要讨论了这些不同的 OP 对映体分离技术，并介绍了它们的应用。
