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氧化锌/金杂化纳米结构:湿化学合成及结构增强的光催化性能。

ZnO/Au hybrid nanoarchitectures: wet-chemical synthesis and structurally enhanced photocatalytic performance.

机构信息

College of Chemistry and Materials Science, Anhui Key Laboratory of Functional Molecular Solids, Anhui Laboratory of Molecular-Based Materials, Anhui Normal University, Wuhu, 241000, P. R. China.

出版信息

Environ Sci Technol. 2009 Dec 1;43(23):8968-73. doi: 10.1021/es902568h.

Abstract

A facile method is introduced to prepare large-area gold-coated ZnO nanorods, featuring the capability to tailor both the spatial distribution and the concentration of metal nanocrystals. The Au nanoparticles-loaded ZnO nanorods exhibit complete catalysis-degradation Rhodamine B within 15 min, which substantially surpass other TiO(2)- and ZnO-based photocatalysts. Furthermore, The ZnO/Au nanocomposites can removal about 91% of environmental persistent 4-chlorophenol from water after 300 min irradiation. The better photocatalytic performance is attributed to the one-dimentional structure of high-quality ZnO nanorods and the large-area noble metal decoration. These promising results would make this photocatalyst an exceptional choice for the environmental purification of organic pollutants in aqueous solution. This approach may also give rise to a new class of multifunctional materials with possible applications in energy-conversion devices, biofunctionalized materials, and infrared-emitting/detecting devices.

摘要

介绍了一种简便的方法来制备大面积的金包覆 ZnO 纳米棒,该方法能够精确调控金属纳米晶的空间分布和浓度。负载 Au 纳米颗粒的 ZnO 纳米棒在 15 分钟内可完全催化降解罗丹明 B,其性能明显优于其他 TiO2 和 ZnO 基光催化剂。此外,ZnO/Au 纳米复合材料在 300 分钟的辐照后可去除水中约 91%的环境持久性 4-氯苯酚。更好的光催化性能归因于高质量 ZnO 纳米棒的一维结构和大面积贵金属修饰。这些有前景的结果将使这种光催化剂成为水溶液中有机污染物环境净化的理想选择。这种方法还可能产生一类新的多功能材料,可应用于能量转换器件、生物功能化材料和红外发光/探测器件。

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