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超声技术在制革工业中的应用:超声处理对基质和物质的影响——新的见解。

Use of ultrasound in leather processing industry: effect of sonication on substrate and substances--new insights.

机构信息

Chemical Engineering Division, Central Leather Research Institute (CLRI), Council of Scientific and Industrial Research (CSIR), Adyar, Chennai,

出版信息

Ultrason Sonochem. 2010 Aug;17(6):1054-9. doi: 10.1016/j.ultsonch.2009.10.012. Epub 2009 Oct 28.

Abstract

Influence of ultrasound (US) on various unit operations in leather processing has been studied with the aim to improve the process efficiency, quality, reduce process time and achieve near-zero discharge levels in effluent streams as a cleaner option. Effect of US on substrate (skin/leather) matrix as well as substances used in different unit operations have been studied and found to be useful in the processing. Absorption of US energy by leather in process vessel at different distances from US source has been measured and found to be significant. Effect of particle-size of different substances due to sonication indicates positive influence on the diffusion through the matrix. Our experimental results suggest that US effect is better realized for the cases with pronounced diffusion hindrance. Influence of US on bioprocessing of leather has been studied and found beneficial. Attempts have also been made to improve the US aided processing using external aids. Operating US in pulse mode operation could be useful in order to reduce the electrical energy consumption. Use of US has also been studied in the preparation of leather auxiliaries involving mass-transfer resistance. Preliminary cost analysis carried out for ultrasound-assisted leather-dyeing process indicates scale-up possibility. Therefore, US application provide improvement in process efficiency as well as making cleaner production methods feasible. Hence, overall results suggest that use of US in leather industry is imminent and potential viable option in near future.

摘要

超声(US)对皮革加工中各种单元操作的影响已经被研究过,目的是提高工艺效率、质量,缩短工艺时间,并在排放物中实现接近零的排放水平,作为更清洁的选择。研究了超声对基质(皮/革)以及不同单元操作中使用的物质的影响,发现其在加工中是有用的。在不同距离的容器中测量了皮革对过程容器中超声能量的吸收,发现吸收量很大。由于超声作用,不同物质的粒径的影响表明对通过基质的扩散有积极的影响。我们的实验结果表明,超声效应在扩散受阻明显的情况下更好地实现。还研究了超声对皮革生物加工的影响,发现其有益。为了提高超声辅助处理的效果,还尝试使用外部辅助手段。采用脉冲模式操作超声可能有助于降低电能消耗。在涉及传质阻力的皮革助剂制备中也研究了超声的使用。对超声辅助皮革染色过程进行了初步成本分析,表明了其具有扩大规模的可能性。因此,超声的应用不仅提高了工艺效率,还使清洁生产方法成为可能。因此,总体结果表明,在皮革工业中使用超声是迫在眉睫的,并且在不久的将来是一种潜在的可行选择。

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