是否被包封？通过扩散核磁共振光谱法绘制溶液中间苯二酚[4]芳烃六聚体胶囊中的醇位点 - Suppr

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超能文献

Encapsulated or not encapsulated? Mapping alcohol sites in hexameric capsules of resorcin[4]arenes in solution by diffusion NMR spectroscopy.

作者信息

Slovak Sarit, Avram Liat, Cohen Yoram

机构信息

School of Chemistry, The Sackler Faculty of Exact Sciences, Tel Aviv University, Ramat Aviv, Tel Aviv 69978, Israel.

出版信息

Angew Chem Int Ed Engl. 2010;49(2):428-31. doi: 10.1002/anie.200904952.

DOI:10.1002/anie.200904952

PMID:19967684

Abstract

摘要

相似文献

Encapsulated or not encapsulated? Mapping alcohol sites in hexameric capsules of resorcin[4]arenes in solution by diffusion NMR spectroscopy.是否被包封？通过扩散核磁共振光谱法绘制溶液中间苯二酚[4]芳烃六聚体胶囊中的醇位点

Angew Chem Int Ed Engl. 2010;49(2):428-31. doi: 10.1002/anie.200904952.

Octahydroxypyridine[4]arene self-assembles spontaneously to form hexameric capsules and dimeric aggregates.八羟基吡啶[4]芳烃能自发自组装形成六聚体胶囊和二聚体聚集体。

Chemistry. 2007;13(27):7659-63. doi: 10.1002/chem.200700461.

Self-recognition, structure, stability, and guest affinity of pyrogallol[4]arene and resorcin[4]arene capsules in solution.均苯三酚[4]芳烃和间苯二酚[4]芳烃胶囊在溶液中的自我识别、结构、稳定性及客体亲和力

J Am Chem Soc. 2004 Sep 22;126(37):11556-63. doi: 10.1021/ja047698r.

The effect of alcohol structures on the interaction mode with the hexameric capsule of resorcin[4]arene.醇结构对间苯二酚[4]芳烃六元环胶囊相互作用模式的影响。

Chemistry. 2012 Jul 2;18(27):8515-20. doi: 10.1002/chem.201102809. Epub 2012 May 25.

Diffusion NMR Reveals the Structures of the Molecular Aggregates of Resorcin[4]arenes and Pyrogallol[4]arenes in Aromatic and Chlorinated Solvents.扩散核磁共振揭示了间苯二酚[4]芳烃和连苯三酚[4]芳烃在芳香族和氯化溶剂中的分子聚集体结构。

J Phys Chem Lett. 2022 Nov 24;13(46):10666-10670. doi: 10.1021/acs.jpclett.2c02936. Epub 2022 Nov 10.

Monomeric, dimeric and hexameric resorcin[4]arene assemblies with alcohols in apolar solvents.在非极性溶剂中，间苯二酚[4]芳烃与醇形成的单体、二聚体和六聚体组装体。

Chem Commun (Camb). 2008 Sep 7(33):3873-5. doi: 10.1039/b803890b. Epub 2008 Jun 27.

Molecules at close range: encapsulated solvent molecules in pyrogallol[4]arene hexameric capsules.近距离的分子：连苯三酚[4]芳烃六聚体胶囊中的包封溶剂分子

Org Lett. 2006 Jan 19;8(2):219-22. doi: 10.1021/ol052459+.

Self-assembly of resorcin[4]arene in the presence of small alkylammonium guests in solution.间苯二酚[4]芳烃在溶液中与小烷基铵客体共存时的自组装。

Org Lett. 2008 Apr 17;10(8):1505-8. doi: 10.1021/ol702912u. Epub 2008 Mar 20.

Bis-resorcin[4]arene Selectively Forms Hexameric Capsules in Apolar Solvents: Evidence from Diffusion NMR.双[4]间苯二酚选择性在非极性溶剂中形成六聚体胶囊：来自扩散 NMR 的证据。

Org Lett. 2018 Jul 6;20(13):3958-3961. doi: 10.1021/acs.orglett.8b01526. Epub 2018 Jun 20.

EPR and NMR investigation on the interactions of nitroxide probes with resorcin[4]arene molecular capsules.电子顺磁共振和核磁共振研究氮氧自由基探针与间苯二酚[4]芳烃分子胶囊的相互作用。

Org Lett. 2009 Dec 17;11(24):5690-3. doi: 10.1021/ol902391u.

引用本文的文献

Molecular Modeling Is Key to Understanding Supramolecular Resorcinarenyl Capsules, Inclusion Complex Formation and Organic Reactions in Nanoconfined Space.分子建模是理解超分子间苯二酚芳烃胶囊、包合物形成以及纳米受限空间中的有机反应的关键。

Molecules. 2025 Jun 11;30(12):2549. doi: 10.3390/molecules30122549.

Combining iminium and supramolecular catalysis for the [4 + 2] cycloaddition of -cinnamaldehydes.将亚胺离子和超分子催化结合用于 -肉桂醛的 [4 + 2] 环加成反应。

Org Biomol Chem. 2022 Aug 24;20(33):6646-6653. doi: 10.1039/d2ob01171a.

Just Add Water: Modulating the Structure-Derived Acidity of Catalytic Hexameric Resorcinarene Capsules.只需加水：调节催化六聚体树脂笼胶囊的结构衍生酸度。

J Am Chem Soc. 2021 Oct 13;143(40):16419-16427. doi: 10.1021/jacs.1c04924. Epub 2021 Sep 30.

Optimized iminium-catalysed 1,4-reductions inside the resorcinarene capsule: achieving >90% ee with proline as catalyst.间苯二酚芳烃胶囊内优化的亚胺离子催化1,4-还原反应：以脯氨酸为催化剂实现>90%的对映体过量值

RSC Adv. 2021 Jul 14;11(40):24607-24612. doi: 10.1039/d1ra04333a. eCollection 2021.

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