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[中国涂料使用过程中挥发性有机化合物的排放估算与预测]

[Estimation and forecast of volatile organic compounds emitted from paint uses in China].

作者信息

Wei Wei, Wang Shu-xiao, Hao Ji-ming

机构信息

Department of Environmental Science and Engineering, Tsinghua University, Beijing 100084, China.

出版信息

Huan Jing Ke Xue. 2009 Oct 15;30(10):2809-15.

Abstract

Based on the current consumptions and forecast consumptions of paints in China, using the volatile organic compounds (VOC) contents of paints calculated as emission factors, an emission inventory model was established to calculate provincial, sector-specific, and species-specific VOC emissions during 2005-2020. The results indicated that the VOC amount emitted from paint use was 1883 kt in 2005, of which aromatics, alcohol compounds, ester compounds, ether compounds and ketone compounds were the main species. The maximum incremental reactivity (MIR,O3/VOC) of VOC emitted in 2005 was about 3.6 g/kg, and the toxic VOC accounted for 31% of the total in weight. The VOC emissions would increase to 5673 kt in 2020 if there were no further control policies and actions taken. Therefore, it is essential to implement the VOC emission control from paint uses as soon as possible. Two control scenarios were developed to evaluate the potential of VOC emission reductions. In 2020, VOC emissions from paint uses might be controlled at 3 519 kt through the improvement of paints quality to the level of that in developed countries in 1990s and installation of waste gas treatment equipments in newly-built factories. VOC emissions could be further reduced to 2243 kt if the quality of decorative paint and wood paint would be improved to the current level of that in developed countries and all factories install waste gas treatment equipments. All these control measures also helpe to reduce the toxicity and atmospheric oxidation reactivity of VOC emissions.

摘要

基于中国涂料的当前消费量和预测消费量,以涂料中的挥发性有机化合物(VOC)含量作为排放因子,建立了一个排放清单模型,以计算2005 - 2020年期间省级、行业特定和物种特定的VOC排放量。结果表明,2005年涂料使用排放的VOC量为1883千吨,其中芳烃、醇类化合物、酯类化合物、醚类化合物和酮类化合物是主要物种。2005年排放的VOC的最大增量反应活性(MIR,O3/VOC)约为3.6克/千克,有毒VOC占总重量的31%。如果不采取进一步的控制政策和行动,到2020年VOC排放量将增加到5673千吨。因此,必须尽快对涂料使用实施VOC排放控制。制定了两种控制方案来评估VOC减排的潜力。到2020年,通过将涂料质量提高到20世纪90年代发达国家的水平,并在新建工厂安装废气处理设备,涂料使用产生的VOC排放可能控制在3519千吨。如果将装饰漆和木器漆的质量提高到发达国家目前的水平,并且所有工厂都安装废气处理设备,VOC排放可进一步降至2243千吨。所有这些控制措施也有助于降低VOC排放的毒性和大气氧化反应活性。

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