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由 1,10-菲咯啉配位的铟硫属元素团簇,[InQ(phen)Cl]4(Q = Se,S),是具有簇到配体电荷转移的无机-有机杂化材料的简化模型。

Indium chalcogenido clusters coordinated by 1,10-phenanthroline, [InQ(phen)Cl]4 (Q = Se, S), a simplified model of inorganic-organic hybrid material with cluster-to-ligand charge transfer.

机构信息

Department of Chemistry and Key Laboratory of Organic Synthesis of Jiangsu Province, Soochow University, Suzhou 215123, People's Republic of China.

出版信息

Inorg Chem. 2010 Jan 18;49(2):353-5. doi: 10.1021/ic901143h.

DOI:10.1021/ic901143h
PMID:20000627
Abstract

Most metal-1,10-phenanthroline-complex-sensitized inorganic semiconductors are multicomponent materials. This fundamental study was devoted to the single-phase materials fused with moieties of the phen complex and inorganic chalcogenide. Compounds 1 and 2 are new types of cubic clusters with cluster-to-ligand charge transfer.

摘要

大多数金属-1,10-菲啰啉配合物敏化的无机半导体都是多组分材料。这项基础研究致力于将菲啰啉配合物和无机硫属元素部分融合到单相材料中。化合物 1 和 2 是具有簇到配体电荷转移的新型立方簇。

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