二芳基二碲化物催化的硅烷在大气氧下氧化为硅醇。
Diorganotelluride-catalyzed oxidation of silanes to silanols under atmospheric oxygen.
机构信息
Department of Materials Chemistry, Tokai University, 317 Nishino, Numazu, Shizuoka 410-0395, Japan.
出版信息
Inorg Chem. 2010 Jan 18;49(2):383-5. doi: 10.1021/ic9022745.
PMID:20014768
Abstract
Diorganotellurides efficiently catalyze the aerobic oxidation of organosilanes under photosensitized conditions to afford the corresponding silanols in excellent yield.
摘要
二芳基二碲化物在光照条件下能高效地催化有机硅烷的有氧氧化反应，以极好的产率得到相应的硅醇。
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