一种邻-二甲苯连接的双(NHC)环芳烷的新键合几何形状：具有螯合(η(1)-NHC)2:η(6)-芳环配体的钌(II)配合物。
A new binding geometry for an ortho-xylylene-linked bis(NHC)cyclophane: a ruthenium(II) complex with a chelating (eta(1)-NHC)2:eta(6)-arene ligand.
机构信息
Chemistry M313, School of Biomedical, Biomolecular and Chemical Sciences, The University of Western Australia, 35 Stirling Hwy, Crawley, WA 6009, Australia.
出版信息
Dalton Trans. 2010 Jan 7(1):70-2. doi: 10.1039/b916498g. Epub 2009 Oct 16.
DOI:10.1039/b916498g
PMID:20023935
Abstract
Using two different reaction procedures, a Ru(II) complex has been isolated that contains an ortho-xylylene-linked bis(NHC)cyclophane (NHC = N-heterocyclic carbene) that binds to the Ru centre through two carbene carbons and one of the arene rings in an eta(6)-mode.
摘要
使用两种不同的反应程序，分离得到一个含有邻-二甲苯连接的双(NHC)环戊二烯基（NHC = 氮杂环卡宾）的 Ru(II) 配合物，该配合物通过两个卡宾碳原子和芳环中的一个以 η(6)-模式结合到 Ru 中心。
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