Chemical Resources Laboratory, Tokyo Institute of Technology, R1-4, 4259 Nagatsuta, Yokohama, 226-8503, Japan.
Dalton Trans. 2010 Jan 14(2):311-28. doi: 10.1039/b911992b. Epub 2009 Oct 5.
A number of transition metal catalysts including early and late transition metals have been investigated for olefin polymerization and copolymerization. Progress of the field in this decade is reviewed, and important topics among them such as binary catalysts and polymerization of new monomers are described in detail. Our recent results on the polymerization of olefins having cycloalkenes and non-conjugated dienes using late transition metal complexes are also mentioned.
许多过渡金属催化剂,包括早期和晚期过渡金属,已经被用于烯烃聚合和共聚反应的研究。本文综述了这十年间该领域的进展,详细描述了其中的一些重要课题,如双金属催化剂和新型单体的聚合。我们最近使用晚期过渡金属配合物聚合环烯烃和非共轭二烯的研究结果也被提及。