主体-客体相互作用对具有环三亚苯型配体的金属超分子组装体的影响。
Host-guest influence on metallo-supramolecular assemblies with a cyclotriveratrylene-type ligand.
机构信息
School of Chemistry, University of Leeds, Leeds, UK LS2 9JT.
出版信息
Dalton Trans. 2010 Jan 14(2):355-7. doi: 10.1039/b914285a. Epub 2009 Sep 8.
DOI:10.1039/b914285a
PMID:20023967
Abstract
The structure-directing effect of guest binding in metallo-supramolecular assemblies of host-type ligands is observed with a 2-D coordination polymer formed between Cd(OAc)(2) and tris(4-pyridylmethylamino)cyclotriguaiacylene in the presence of the globular guest o-carborane, and a trinuclear Cd(II) complex formed in solution in the absence of the bulky guest.
摘要
在球形客体 o-卡硼烷的存在下，Cd(OAc)(2)和三(4-吡啶基甲基氨基)环三[1.1.1] 丙烷与主体型配体形成的 2-D 配位聚合物中观察到客体结合的结构导向效应，而在不存在大体积客体的情况下，在溶液中形成三核 Cd(II)配合物。
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