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双(恶唑啉基)苯基过渡金属配合物:不对称催化和金属的一些反应。

Bis(oxazolinyl)phenyl transition-metal complexes: asymmetric catalysis and some reactions of the metals.

机构信息

Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Chikusa, Nagoya, 464-8603, Japan.

出版信息

Chem Commun (Camb). 2010 Jan 14;46(2):203-12. doi: 10.1039/b918923h. Epub 2009 Nov 19.

Abstract

Several transition-metal complexes that bind the bis(oxazolinyl)phenyl moiety as a tridentate ligand have been prepared to showcase their highly potent activities for asymmetric catalysis in conjugate reductions, reductive aldol reactions, direct aldol reactions and hydrogenation reactions. Some reactions of the metals were also examined.

摘要

已经制备了几种过渡金属配合物,它们将双(恶唑啉基)苯基部分作为三齿配体结合,以展示它们在共轭还原、还原羟醛反应、直接羟醛反应和氢化反应中具有非常高的不对称催化活性。还研究了一些金属的反应。

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