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利用稻壳灰基催化剂通过类 Fenton 过程对酸性红 1 进行脱色。

Decolorization of Acid Red 1 by Fenton-like process using rice husk ash-based catalyst.

机构信息

School of Chemical Engineering, Engineering Campus, Universiti Sains Malaysia, 14300 Nibong Tebal, Penang, Malaysia.

出版信息

J Hazard Mater. 2010 Apr 15;176(1-3):938-44. doi: 10.1016/j.jhazmat.2009.11.130. Epub 2009 Dec 1.

Abstract

The decolorization of Acid Red 1 (AR1) in aqueous solution was investigated by Fenton-like process. The effect of different reaction parameters such as different iron ions loading on rice husk ash (RHA), dosage of catalyst, initial pH, the initial hydrogen peroxide concentration (H(2)O(2)), the initial concentration of AR1 (AR1) and the reaction temperature on the decolorization of AR1 was studied. The optimal reacting conditions were found to be 0.070 wt.% of iron (III) oxide loading on RHA, dosage of catalyst=5.0 g L(-1), initial pH=2.0, H(2)O(2)=8 mM, AR1=50 mg L(-1) at temperature 30 degrees C. Under optimal condition, 96% decolorization efficiency of AR1 was achieved within 120 min of reaction.

摘要

通过类芬顿反应研究了水溶液中酸性红 1(AR1)的脱色情况。考察了不同反应参数,如不同铁离子负载量对稻壳灰(RHA)、催化剂用量、初始 pH 值、初始过氧化氢浓度(H(2)O(2))、AR1 的初始浓度(AR1)和反应温度对 AR1 脱色的影响。发现最佳反应条件为:RHA 中铁(III)氧化物的负载量为 0.070wt.%,催化剂用量=5.0g/L,初始 pH 值=2.0,H(2)O(2)=8mM,AR1=50mg/L,温度为 30℃。在最佳条件下,反应 120min 后 AR1 的脱色率达到 96%。

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