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芬顿法对水溶液中孔雀石绿的降解

Degradation of malachite green in aqueous solution by Fenton process.

作者信息

Hameed B H, Lee T W

机构信息

School of Chemical Engineering, Engineering Campus, Universiti Sains Malaysia, Nibong Tebal, Penang, Malaysia.

出版信息

J Hazard Mater. 2009 May 30;164(2-3):468-72. doi: 10.1016/j.jhazmat.2008.08.018. Epub 2008 Aug 15.

Abstract

In this study, advanced oxidation process utilizing Fenton's reagent was investigated for degradation of malachite green (MG). The effects of different reaction parameters such as the initial MG concentration, initial pH, the initial hydrogen peroxide concentration, the initial ferrous concentration and the reaction temperature on the oxidative degradation of MG have been investigated. The optimal reacting conditions were experimentally found to be pH 3.40, initial hydrogen peroxide concentration=0.50mM and initial ferrous concentration=0.10mM for initial MG concentration of 20mg/L at 30 degrees C. Under optimal conditions, 99.25% degradation efficiency of dye in aqueous solution was achieved after 60 min of reaction.

摘要

本研究考察了利用芬顿试剂的高级氧化过程对孔雀石绿(MG)的降解情况。研究了不同反应参数,如初始MG浓度、初始pH值、初始过氧化氢浓度、初始亚铁浓度和反应温度对MG氧化降解的影响。实验发现,对于30℃下初始MG浓度为20mg/L的情况,最佳反应条件为pH 3.40、初始过氧化氢浓度 = 0.50mM和初始亚铁浓度 = 0.10mM。在最佳条件下,反应60分钟后,水溶液中染料的降解效率达到99.25%。

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