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基于树胶阿拉伯半互穿水凝胶的银纳米粒子设计。

Designing of silver nanoparticles in gum arabic based semi-IPN hydrogel.

机构信息

Polymer Research Unit, Department of Chemistry, Utkal University, Vani Vihar, Bhubaneswar 751004, India.

出版信息

Int J Biol Macromol. 2010 Mar 1;46(2):237-44. doi: 10.1016/j.ijbiomac.2009.12.014. Epub 2010 Jan 8.

Abstract

Semi-interpenetrating network (SISH-GA) composed of gum arabic and crosslinked copolymer of poly(2-hydroxyethyl methacrylate-co-acrylic acid) was synthesized in the presence of initiator ammonium persulfate (APS), crosslinker N,N'-methylene bis acrylamide (MBA), catalyzed by [CuSO4/glycine] chelate complex and finally loaded nanoparticle inside the networks via in situ reduction of silver nitrate (AgNO3) using trisodium citrate (Na3C6H5O7) as reducing agent. Characterization of the product was performed along with its degradability in Escherichia coli medium.

摘要

半互穿网络(SISH-GA)由阿拉伯胶和交联共聚物聚(2-羟乙基甲基丙烯酸酯-共-丙烯酸)组成,在引发剂过硫酸铵(APS)、交联剂 N,N'-亚甲基双丙烯酰胺(MBA)、[CuSO4/甘氨酸]配合物催化剂的存在下合成,最后通过使用柠檬酸三钠(Na3C6H5O7)作为还原剂原位还原硝酸银(AgNO3)将纳米颗粒载入网络中。对产物进行了表征,并在大肠杆菌培养基中进行了降解性研究。

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