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通过电解法从胶束强化超滤浓缩液中回收镉离子

[Recovery of Cd2+ by an electrolytic process from the concentrated solution of micellar enhanced ultrafiltration].

作者信息

Lin Dan, Zeng Guang-Ming, Huang Jin-Hui, Fang Yao-Yao, Qu Yun-Huan, Li Xue, Luo Fang

机构信息

College of Environmental Science and Engineering, Hunan University, Changsha 410082, China.

出版信息

Huan Jing Ke Xue. 2009 Nov;30(11):3347-52.

Abstract

Micellar enhanced ultrafiltration (MEUF) is a new method which is based on the surfactant of the unique characteristic of parental molecular structure that can remove heavy metals in the water. The concentrated solution by dealing with the MEUF contains high concentration of heavy metal ions, so it must be need for further processing. The electrolysis method was employed to recovery Cd2+ from the concentrated solution of micellar enhanced ultrafiltration (MEUF). Effects of type of electrode, electrolysis voltage (U) and time (t), solution pH, surfactant to Cd2+ molar ratio ([SDS]/[Cd2+]) on Cd2+ recovery efficiency were investigated. The study found that the surfactant had some effect of resistance to electrolysis process. The optimum experimental conditions were obtained: stainless steel (anode)-graphite (cathode), U = 2.8 V, t = 100 min, pH = 4, [SDS]/[Cd2+] = 5 ([SDS] = 8.5 mmol/L constant). And the recovery efficiency of Cd2+ in the concentrated solution was 50.26%.

摘要

胶束增强超滤(MEUF)是一种基于表面活性剂独特双亲分子结构特性的新方法,可用于去除水中的重金属。通过胶束增强超滤处理后的浓缩溶液含有高浓度的重金属离子,因此必须进行进一步处理。采用电解法从胶束增强超滤(MEUF)浓缩液中回收Cd2+。研究了电极类型、电解电压(U)和时间(t)、溶液pH值、表面活性剂与Cd2+摩尔比([SDS]/[Cd2+])对Cd2+回收效率的影响。研究发现表面活性剂对电解过程有一定的阻碍作用。获得了最佳实验条件:不锈钢(阳极)-石墨(阴极),U = 2.8 V,t = 100 min,pH = 4,[SDS]/[Cd2+] = 5([SDS] = 8.5 mmol/L恒定)。浓缩液中Cd2+的回收效率为50.26%。

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