烯丙基取代基对环 closing metathesis 的影响：stagonolide B 和 4-epi-stagonolide B 的全合成。
Effect of the allylic substituents on ring closing metathesis: the total synthesis of stagonolide B and 4-epi-stagonolide B.
机构信息
National Chemical Laboratory, Dr. Homi Bhabha Road, Pune, 411 008, India.
出版信息
Org Biomol Chem. 2010 Jan 21;8(2):398-406. doi: 10.1039/b916198h. Epub 2009 Oct 29.
DOI:10.1039/b916198h
PMID:20066276
Abstract
The total syntheses of stagonolide B and its 4-epimer were carried out to probe into how the relative stereochemistry of allylic hydroxy groups and their protecting groups influence the efficiency of the ring closing metathesis.
摘要
对扇贝醇 B 及其 4-差向异构体进行了全合成，以探讨烯丙位羟基及其保护基的相对立体化学如何影响环 closing metathesis 的效率。
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