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一种在低温下制备 TiO2 薄膜的新方法及其在光催化降解甲基橙中的应用。

A novel approach of preparing TiO2 films at low temperature and its application in photocatalytic degradation of methyl orange.

机构信息

Environmental Science Research Institute, Huazhong University of Science and Technology, 1037 Luoyu Road, Wuhan 430074, PR China.

出版信息

J Hazard Mater. 2010 May 15;177(1-3):750-4. doi: 10.1016/j.jhazmat.2009.12.095. Epub 2010 Jan 4.

DOI:10.1016/j.jhazmat.2009.12.095
PMID:20071078
Abstract

Here we introduce a novel approach of preparing TiO(2) films on conductive substrates at low temperature by electrophoretic deposition method without successive calcinate treatment. The photocatalytic activity of the non-calcinated TiO(2) film was evaluated by degradation rate of methyl orange (MO). We found that the degradation rate of MO increased with the amount of TiO(2), and it was higher in both acidic and alkaline media than under neural condition. In addition, lower pH was more favorable for the degradation of MO. The photocatalytic degradation of MO could be described as pseudo-first order reactions. When the initial concentration of MO increased from 1mg/L to 10mg/L, the highest degradation rate was achieved at 5mg/L. The apparent reaction rate constant was calculated to be 0.0098 min(-1).

摘要

在这里,我们介绍了一种在低温下通过电泳沉积法在导电基底上制备 TiO(2)薄膜的新方法,无需进行连续煅烧处理。通过甲基橙 (MO) 的降解率评估了未经煅烧的 TiO(2)薄膜的光催化活性。我们发现 MO 的降解率随 TiO(2)的量增加而增加,在酸性和碱性介质中的降解率均高于中性条件下。此外,较低的 pH 值更有利于 MO 的降解。MO 的光催化降解可以用伪一级反应来描述。当 MO 的初始浓度从 1mg/L 增加到 10mg/L 时,在 5mg/L 时达到最高降解率。计算得到的表观反应速率常数为 0.0098 min(-1)。

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