National Nanotechnology Center (NANOTEC), National Science and Technology Development Agency (NSTDA), 111 Thailand Science Park, Phahonyothin Rd., Klong Luang, Pathumthani 12120, Thailand.
Bioresour Technol. 2010 May;101(10):3765-7. doi: 10.1016/j.biortech.2009.12.079. Epub 2010 Jan 15.
The solid oxide catalysts derived from waste shells of egg, golden apple snail, and meretrix venus were employed to produce biodiesel from transesterification of palm olein oil. The shell materials were calcined in air at 800 degrees C with optimum time of 2-4h to transform calcium species in the shells into active CaO catalysts. All catalysts showed the high biodiesel production activity over 90% fatty acid methyl ester (FAME) in 2h, whilst the eggshell-derived catalyst showed comparable activity to the one derived from commercial CaCO(3). The catalytic activity was in accordance with the surface area of and the Ca content in the catalysts.
采用废鸡蛋壳、福寿螺和西施舌壳制备的固体氧化物催化剂,用于通过棕榈油油脂的酯交换反应来生产生物柴油。壳材料在空气中 800°C 下煅烧,最佳时间为 2-4 小时,将壳中的钙物质转化为活性 CaO 催化剂。所有催化剂在 2 小时内都表现出超过 90%的脂肪酸甲酯(FAME)的高生物柴油产率,而鸡蛋壳衍生的催化剂表现出与商业 CaCO3 衍生的催化剂相当的活性。催化活性与催化剂的表面积和 Ca 含量相符。