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Ag@TiO2 核壳纳米复合纳米线的制备及增强光催化活性。

Preparation and enhanced photocatalytic activity of Ag@TiO2 core-shell nanocomposite nanowires.

机构信息

State Key Laboratory of Advanced Technology for Material Synthesis and Processing, Wuhan University of Technology, Luoshi Road 122#, Wuhan 430070, Hubei, PR China.

出版信息

J Hazard Mater. 2010 May 15;177(1-3):971-7. doi: 10.1016/j.jhazmat.2010.01.013. Epub 2010 Jan 11.

Abstract

Ag@TiO(2) core-shell nanocomposite nanowires were synthesized via a vapor-thermal method using Ag nanowires as templates and tetrabutyl titanate (TBOT) as precursors at 150 degrees C for 10h. The as-prepared samples were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy and nitrogen adsorption-desorption isotherms. The photocatalytic activity of the as-prepared samples was evaluated by photocatalytic decolorization of Rhodamine B (RhB) aqueous solution at ambient temperature under UV-light irradiation. The results show that the Ag@TiO(2) core-shell nanowires exhibit highly efficient and recyclable photocatalytic activity for the degradation of RhB aqueous solution. Moreover, in contrast to the discrete nanoparticles, the Ag@TiO(2) nanowires can be readily separated from the treated solution by natural settlement after photocatalytic reaction.

摘要

Ag@TiO(2) 核壳纳米复合纳米线通过气相热法合成,以 Ag 纳米线为模板,四丁醇钛(TBOT)为前驱体,在 150°C 下反应 10 小时。通过 X 射线衍射、扫描电子显微镜、透射电子显微镜和氮气吸附-脱附等温线对所制备的样品进行了表征。通过在室温下在紫外光照射下光催化降解罗丹明 B(RhB)水溶液评价了所制备样品的光催化活性。结果表明,Ag@TiO(2)核壳纳米线对 RhB 水溶液的降解表现出高效和可重复使用的光催化活性。此外,与离散的纳米颗粒相比,Ag@TiO(2)纳米线在光催化反应后可以通过自然沉降很容易地从处理过的溶液中分离出来。

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