Howard Alan G
School of Chemistry, University of Southampton, Southampton, SO17 1BJ, UK.
J Environ Monit. 2010 Jan;12(1):135-42. doi: 10.1039/b913681a. Epub 2009 Nov 30.
Technologies based on nanomaterials are developing daily, finding applications as diverse as new sensors for improved monitoring and detection, new medical imaging techniques, novel approaches to the treatment and remediation of contaminated land and green technologies for chemical production. An inevitable consequence of Man's exploitation of nanotechnology is both the deliberate and accidental release of manufactured nanomaterials into the environment. This presents the analytical science community with a challenge for which it is, at present, poorly prepared--the quantification of specific nanoparticles in the environment. The problem is the development of trace analysis methods targeted at solid phase species, rather than the dissolved species measured, for example, in a typical pesticide residue analysis. This will require the adoption of radically different approaches and techniques, many of which will be unfamiliar to the conventionally trained environmental analyst. This paper sets out to give a very brief overview of the techniques that are available, specifically questioning their suitability for the quantification of man-made nanoparticles in the aquatic environment. Suggestions are made as to how these techniques might be transferred from the characterization of synthetic products to the field of trace analysis. The analytical community is presented with a new frontier of environmental investigation that can only commence with the development of innovative approaches to the quantitative measurement of man-made nanomaterials in the environment.
基于纳米材料的技术日新月异,其应用领域广泛,涵盖用于改进监测与检测的新型传感器、新的医学成像技术、治理受污染土地的新颖方法以及用于化学生产的绿色技术等。人类对纳米技术的开发利用不可避免地导致人造纳米材料有意或无意地释放到环境中。这给分析科学界带来了一项挑战,而目前他们对此准备不足——即对环境中特定纳米颗粒进行定量分析。问题在于要开发针对固相物质的痕量分析方法,而非像在典型的农药残留分析中那样测量溶解态物质。这将需要采用截然不同的方法和技术,其中许多对于传统培训的环境分析师来说是陌生的。本文旨在简要概述现有的技术,特别探讨它们在定量分析水环境中人造纳米颗粒方面的适用性。文中还就如何将这些技术从合成产品的表征领域应用到痕量分析领域提出了建议。分析界面临着环境调查的新前沿领域,而这只能从开发用于定量测量环境中人造纳米材料的创新方法开始。