Department of Chemistry, Memorial University of Newfoundland, St. John's, NL, Canada A1B 3X7.
Org Lett. 2010 Feb 19;12(4):704-7. doi: 10.1021/ol9026683.
An acetylenic phenyldithiafulvene was developed as a versatile synthon for diverse TTFV-based macromolecular scaffolds. Through different coupling reaction sequences, shape-persistent macrocycles and linear TTFV-embedded polymers have been obtained and thereafter characterized by spectroscopic and voltammetric analyses. The TTFV polymer thin films generated via electropolymerization of a dithiafulvenyl-end-capped diyne monomer showed promising prospects in electrochromic and redox switchable molecular devices.
一种炔基苯二硫杂富烯被开发为用于各种基于四硫富瓦烯的大分子支架的多功能合成子。通过不同的偶联反应序列，得到了形状保持的大环和线性嵌入四硫富瓦烯的聚合物，并通过光谱和伏安分析进行了表征。通过二硫杂富烯端封二炔单体的电聚合生成的四硫富瓦烯聚合物薄膜在电致变色和氧化还原开关分子器件中显示出有前景的应用。
