School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, People's Republic of China.
ACS Nano. 2010 Feb 23;4(2):1202-8. doi: 10.1021/nn901635f.
Tin oxide is a unique material of widespread technological applications, particularly in the field of environmental functional materials. New strategies of fractal assessment for tin dioxide thin films formed at different substrate temperatures are of fundamental importance in the development of microdevices, such as gas sensors for the detection of environmental pollutants. Here, tin dioxide thin films with interesting fractal features were successfully prepared by pulsed laser deposition techniques under different substrate temperatures. Fractal method has been first applied to the evaluation of this material. The measurements of carbon monoxide gas sensitivity confirmed that the gas sensing behavior is sensitively dependent on fractal dimensions, fractal densities, and average sizes of the fractal clusters. The random tunneling junction network mechanism was proposed to provide a rational explanation for this gas sensing behavior. The formation process of tin dioxide nanocrystals and fractal clusters could be reasonably described by a novel model.
氧化锡是一种具有广泛技术应用的独特材料,特别是在环境功能材料领域。在开发微器件(例如用于检测环境污染物的气体传感器)方面,对于在不同衬底温度下形成的二氧化锡薄膜进行分形评估的新策略具有重要意义。在这里,通过脉冲激光沉积技术在不同的衬底温度下成功制备了具有有趣分形特征的氧化锡薄膜。分形方法首次被应用于该材料的评估。一氧化碳气体灵敏度的测量结果证实,气体传感行为对分形维数、分形密度和分形团簇的平均尺寸敏感。提出了随机隧道结网络机制来为这种气体传感行为提供合理的解释。通过一个新模型可以合理地描述氧化锡纳米晶和分形团簇的形成过程。