作为氧化还原活性、非中性配体的 Verdazyl 自由基：电子贫化和电子富化的钌双（β-二酮）共配体的功能对比电子结构。
Verdazyl radicals as redox-active, non-innocent, ligands: contrasting electronic structures as a function of electron-poor and electron-rich ruthenium bis(beta-diketonate) co-ligands.
机构信息
Department of Chemistry, University of Victoria, PO Box 3065 STN CSC, Victoria, BC, Canada.
出版信息
Chem Commun (Camb). 2010 Feb 7;46(5):773-5. doi: 10.1039/b919920a. Epub 2009 Dec 11.
DOI:10.1039/b919920a
PMID:20087516
Abstract
Spectroscopic, structural, and computational studies of verdazyl radical-ruthenium complexes reveal the verdazyl to be a redox-active and non-innocent ligand. The ensuing delocalization of charge is highly sensitive to the nature of the beta-diketonate co-ligands.
摘要
光谱学、结构和计算研究表明，紫嗪自由基-钌配合物中的紫嗪基是一个氧化还原活性且非惰性的配体。随之而来的电荷离域对β-二酮配体的性质非常敏感。
Zotero 插件