在无溶剂和无酸条件下 Au/Ag 共催化的醛肟到酰胺的重排反应。
Au/Ag-cocatalyzed aldoximes to amides rearrangement under solvent- and acid-free conditions.
机构信息
School of Chemistry, University of St. Andrews, St. Andrews KY16 9ST, UK.
出版信息
J Org Chem. 2010 Feb 19;75(4):1197-202. doi: 10.1021/jo902461a.
PMID:20102222
Abstract
The gold/silver-cocatalyzed conversion of aldoximes into primary amides is reported. The reaction, which proceeds under neat and acid-free conditions, allows for the conversion of a range of aldoximes, and is a rare example of cooperative catalysis involving well-defined gold species.
摘要
报道了金/银共催化醛肟转化为伯酰胺的反应。该反应在无酸和无溶剂条件下进行，能够实现一系列醛肟的转化，是涉及明确金物种的协同催化的罕见实例。
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