SnCl2/TiCl3 介导的肟在水溶剂中的脱肟反应。
SnCl2/TiCl3-mediated deoximation of oximes in an aqueous solvent.
机构信息
Department of Chemistry, National Changhua University of Education, Changhua 50007, Taiwan.
出版信息
Molecules. 2012 Mar 1;17(3):2464-73. doi: 10.3390/molecules17032464.
Abstract
A simple procedure for SnCl(2)/TiCl(3)-mediated deoximation of ketoximes in an aqueous solvent is reported. Under the conditions developed in this effort, various ketones and aldehydes are produced in good to excellent yields.
摘要
报道了一种在水溶剂中用 SnCl(2)/TiCl(3)介导酮肟脱肟的简单方法。在本研究中开发的条件下，各种酮和醛以良好到优异的产率得到生成。
相似文献
1
SnCl2/TiCl3-mediated deoximation of oximes in an aqueous solvent.
Molecules. 2012 Mar 1;17(3):2464-73. doi: 10.3390/molecules17032464.
2
Amorphous TiO2 coated into periodic mesoporous organosilicate channels as a new binary photocatalyst for regeneration of carbonyl compounds from oximes under sunlight irradiation.
Org Biomol Chem. 2013 Jan 21;11(3):416-9. doi: 10.1039/c2ob26907d. Epub 2012 Dec 3.
3
Selective monobenzoylation of 1,2- and 1,3-diols catalyzed by Me2SnCl2 in water (organic solvent free) under mild conditions.
J Org Chem. 2012 Jan 6;77(1):754-9. doi: 10.1021/jo202136a. Epub 2011 Dec 2.
4
Beckmann rearrangement of ketoximes induced by phenyl dichlorophosphate at ambient temperature.
Molecules. 2012 Nov 20;17(11):13662-72. doi: 10.3390/molecules171113662.
5
SnCl(4)- and TiCl(4)-catalyzed anomerization of acylated O- and S-glycosides: analysis of factors that lead to higher α:β anomer ratios and reaction rates.
J Org Chem. 2010 Oct 15;75(20):6747-55. doi: 10.1021/jo101090f.
6
Solvent free, microwave assisted conversion of aldehydes into nitriles and oximes in the presence of NH2OH x HCl and TiO2.
Molecules. 2009 Dec 29;15(1):94-9. doi: 10.3390/molecules15010094.
7
Novel carbonyl allylation mediated by SnCl2/TiCl3 in water.
Org Lett. 2003 May 29;5(11):1833-5. doi: 10.1021/ol034267p.
8
The allylation reactions of aromatic aldehydes and ketones with tin dichloride in water.
Ultrason Sonochem. 2010 Jan;17(1):58-60. doi: 10.1016/j.ultsonch.2009.05.008. Epub 2009 May 18.
9
Microwave-Assisted Condensation Reactions of Acetophenone Derivatives and Activated Methylene Compounds with Aldehydes Catalyzed by Boric Acid under Solvent-Free Conditions.
Molecules. 2015 Jun 23;20(6):11617-31. doi: 10.3390/molecules200611617.
10
Ultrasound Assisted Synthesis of Quinoline Derivatives in the Presence of SnCl2·2H2O as a Precatalyst in Water: Evaluation of their Antibacterial Activities.
Mini Rev Med Chem. 2018;18(10):895-903. doi: 10.2174/1389557517666170412112619.
引用本文的文献
1
Synthesis, Spectroscopic, Structural and Quantum Chemical Studies of a New Imine Oxime and Its Palladium(II) Complex: Hydrolysis Mechanism.
Molecules. 2016 Jan 21;21(1):E52. doi: 10.3390/molecules21010052.
本文引用的文献
1
Water-medium and solvent-free organic reactions over a bifunctional catalyst with Au nanoparticles covalently bonded to HS/SO3H functionalized periodic mesoporous organosilica.
J Am Chem Soc. 2011 Aug 3;133(30):11632-40. doi: 10.1021/ja203450g. Epub 2011 Jul 12.
2
Rational catalysis design on the basis of mechanistic understanding: highly efficient Pd-catalyzed cyanation of aryl bromides with NaCN in recyclable solvents.
J Am Chem Soc. 2011 Jul 20;133(28):10999-1005. doi: 10.1021/ja2042035. Epub 2011 Jun 23.
3
Sodium nitrite catalyzed aerobic oxidative deoximation under mild conditions.
J Org Chem. 2011 Jun 3;76(11):4665-8. doi: 10.1021/jo102571e. Epub 2011 May 13.
4
One-pot metal-free syntheses of acetophenones from styrenes through aerobic photo-oxidation and deiodination with iodine.
Org Lett. 2011 May 20;13(10):2576-9. doi: 10.1021/ol200681k. Epub 2011 Apr 27.
5
Palladium-catalyzed oxidative coupling of trialkylamines with aryl iodides leading to alkyl aryl ketones.
Org Lett. 2011 May 6;13(9):2184-7. doi: 10.1021/ol200404z. Epub 2011 Apr 7.
6
Dehydrogenative oxidation of primary and secondary alcohols catalyzed by a Cp*Ir complex having a functional C,N-chelate ligand.
Org Lett. 2011 May 6;13(9):2278-81. doi: 10.1021/ol2005424. Epub 2011 Apr 7.
7
Tin mediated allylation reactions of enol ethers in water.
Org Lett. 2011 Jan 21;13(2):332-5. doi: 10.1021/ol102825t. Epub 2010 Dec 13.
8
Hydrogen-bonding-promoted oxidative addition and regioselective arylation of olefins with aryl chlorides.
J Am Chem Soc. 2010 Nov 24;132(46):16689-99. doi: 10.1021/ja1081926. Epub 2010 Oct 28.
9
An expedient reductive method for conversion of ketoximes to the corresponding carbonyl compounds.
Tetrahedron Lett. 2010 Jul 1;51(27):3555-3557. doi: 10.1016/j.tetlet.2010.04.131.
10
Au/Ag-cocatalyzed aldoximes to amides rearrangement under solvent- and acid-free conditions.
J Org Chem. 2010 Feb 19;75(4):1197-202. doi: 10.1021/jo902461a.
Zotero 插件