P-C 二分法：不同的铁（I）介导的炔烃和膦炔环齐聚反应。
P-C dichotomy: divergent iron(-I)-mediated alkyne and phosphaalkyne cycloligomerisations.
机构信息
University of Münster, Institute of Inorganic and Analytical Chemistry, Corrensstr. 30, D-48149 Münster, Germany.
出版信息
Dalton Trans. 2010 Feb 14;39(6):1453-6. doi: 10.1039/b923663p. Epub 2009 Dec 4.
DOI:10.1039/b923663p
PMID:20104301
Abstract
In contrast to the recently reported cyclodimerisations of phosphaalkynes, alkynes preferably trimerise at the same low-valent iron(-I) centre.
摘要
与最近报道的膦炔的环二聚反应相反，炔烃在相同的低价铁(-I)中心更倾向于三聚。
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