分子构造学：混合价态 Fe(II)/Fe(III) 固溶体的晶体工程。
Molecular tectonics: crystal engineering of mixed valence Fe(II)/Fe(III) solid solutions.
机构信息
Laboratoire de Chimie de Coordination Organique, UMR CNRS 7140, Université de Strasbourg, Institut Le Bel, 4, rue Blaise Pascal, F-67000 Strasbourg, France.
出版信息
Chem Commun (Camb). 2010 Feb 14;46(6):868-70. doi: 10.1039/b919478a. Epub 2009 Nov 30.
Based on isostructurality between crystals formed upon combining the dicationic tecton 2 with either M(3)Fe(III)(CN)(6) or M(4)Fe(II)(CN)(6) (M = Cs), a rare example of an H-bonded mixed valence Fe(ii)-Fe(iii) solid solution ((Cs(2)2(3)-Fe(II)(CN)(6))(0.83)(2(3)-Fe(III)(CN)(6))(0.17))) and curious necklace-like composite crystals were generated.
基于与二价阳离子构筑体 2 分别结合 M(3)Fe(III)(CN)(6) 或 M(4)Fe(II)(CN)(6)（M = Cs）所形成的晶体的同结构特征，得到了一个罕见的氢键混合价态 Fe(ii)-Fe(iii) 固态溶液（((Cs(2)2(3)-Fe(II)(CN)(6))(0.83)(2(3)-Fe(III)(CN)(6))(0.17)))和奇特的项链状复合晶体的实例。
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