方便获得商业上可用且廉价的起始原料制备无水四氯化钍配合物 ThCl(4)(DME)(2)、ThCl(4)(1,4-二氧六环)(2) 和 ThCl(4)(THF)(3.5)。
Convenient access to the anhydrous thorium tetrachloride complexes ThCl(4)(DME)(2), ThCl(4)(1,4-dioxane)(2) and ThCl(4)(THF)(3.5) using commercially available and inexpensive starting materials.
机构信息
Los Alamos National Laboratory, Los Alamos, NM 87545, USA.
出版信息
Chem Commun (Camb). 2010 Feb 14;46(6):919-21. doi: 10.1039/b923558b. Epub 2010 Jan 11.
DOI:10.1039/b923558b
PMID:20107650
Abstract
Anhydrous thorium tetrachloride complexes ThCl(4)(DME)(2), ThCl(4)(1,4-dioxane)(2), and ThCl(4)(THF)(3.5) have been easily accessed from inexpensive, commercially available reagents under mild conditions and serve as excellent precursors to a variety of thorium(iv) halide, alkoxide, amide and organometallic compounds.
摘要
无水四氯化钍配合物 ThCl(4)(DME)(2)、ThCl(4)(1,4-二氧六环)(2) 和 ThCl(4)(THF)(3.5) 可从廉价、市售的试剂在温和条件下容易获得，并且作为各种四价钍卤化物、烷氧基化物、酰胺和有机金属化合物的优异前体。
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