双功能沸石负载金属催化剂上的水相酚的加氢脱氧和偶联反应。
Hydrodeoxygenation and coupling of aqueous phenolics over bifunctional zeolite-supported metal catalysts.
机构信息
School of Chemical & Biomolecular Engineering, Georgia Institute of Technology, 311 Ferst Drive NW, Atlanta, GA 30332, USA.
出版信息
Chem Commun (Camb). 2010 Feb 21;46(7):1038-40. doi: 10.1039/b918209h. Epub 2009 Dec 16.
DOI:10.1039/b918209h
PMID:20126705
Abstract
Pt supported on HY zeolite is successfully used as a bifunctional catalyst for phenol hydrodeoxygenation in a fixed-bed configuration at elevated hydrogen pressures, leading to hydrogenation-hydrogenolysis ring-coupling reactions producing hydrocarbons, some with enhanced molecular weight.
摘要
在高压氢气条件下，负载于 HY 沸石上的 Pt 成功用作苯酚加氢脱氧的双功能催化剂，在固定床配置中进行，导致加氢-氢解环偶联反应生成烃类，其中一些具有增强的分子量。
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