School of Chemistry, The University of Manchester, Oxford Road, Manchester, UK M13 9PL.
Chem Commun (Camb). 2010 Feb 21;46(7):1047-9. doi: 10.1039/b922257j. Epub 2010 Jan 13.
We present the first in situ observations of the growth of a zeotype using atomic force microscopy. The {100} face of sodalite zincophosphate grows by a spiral growth mechanism forming an interlaced spiral pattern. This is caused by the anisotropic growth of sub-steps formed at the dislocation, which is related to the different condensation rates of zinc and phosphorus.
我们首次利用原子力显微镜原位观察沸石型的生长。方沸石锌磷酸盐的{100}面通过螺旋生长机制生长,形成交错的螺旋图案。这是由位错处形成的亚台阶的各向异性生长引起的,这与锌和磷的不同凝结速率有关。