Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai (200433), China.
Chem Commun (Camb). 2010 Feb 21;46(7):1100-2. doi: 10.1039/b917987a. Epub 2009 Dec 23.
The layered-solvothermal synthesis of zinc acetate dihydrate with 5-phosphonobenzene-1,3-dicarboxylic acid yields a three-dimensional rutile-type porous metal-organic framework, which is an anionic open-framework containing local proton transfer with hydrated protons and showing excellent size-selective properties.
采用层层溶剂热法合成了三水合醋酸锌与 5-膦酸基苯-1,3-二羧酸的配位聚合物，得到了一种具有锐钛矿型三维多孔结构的金属有机骨架材料。该材料是一种阴离子型的开放式骨架结构，其中包含局部质子转移和水合质子，表现出优异的尺寸选择性。
