亲核杂环卡宾作为一种新型氰基丙烯酸酯环丙烷化反应催化剂。
Nucleophilic heterocyclic carbene as a novel catalyst for cyclopropanation of cyano acrylates.
机构信息
Organic Chemistry Division, NIIST, Thiruvananthapuram, Kerala, India.
出版信息
Org Biomol Chem. 2010 Feb 21;8(4):901-5. doi: 10.1039/b916343c. Epub 2009 Dec 16.
DOI:10.1039/b916343c
PMID:20135050
Abstract
Nucleophilic heterocyclic carbenes (NHCs) have been used for the first time as catalysts in the cyclopropanation of ethyl cyanocinnamates with phenacyl bromide by Michael-initiated ring-closure (MIRC).
摘要
亲核杂环卡宾（NHCs）首次被用作催化剂，通过迈克尔加成环化（MIRC）催化氰基肉桂酸乙酯与苯乙酮溴的环丙烷化反应。
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