Department for Theoretical Physics, Odessa National University, Dvoryanskaya 2, 65026 Odessa, Ukraine.
J Phys Chem B. 2010 Mar 4;114(8):2852-5. doi: 10.1021/jp911897k.
The unified geometrical interpretation of the linear character of the Zeno-line (unit compressibility line Z = 1) and the rectilinear diameter is proposed. We show that recent findings about the properties of the Zeno-line and striking correlation with the rectilinear diameter line as well as other empirical relations can be naturally considered as the consequences of the projective isomorphism between the real molecular fluids and the lattice gas (Ising) model.
提出了齐诺线(单位压缩性线 Z=1)的线性特征和直线直径的统一几何解释。我们表明,最近关于齐诺线性质的发现以及与直线直径线以及其他经验关系的惊人相关性,可以自然地视为真实分子流体和晶格气体(Ising)模型之间射影同构的结果。