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合成与发光铈氧化物纳米粒子的特性。

Synthesis and characterization of luminescent cerium oxide nanoparticles.

机构信息

University of Florida, Department of Materials Science & Engineering, Rhines Hall, PO Box 116400, Gainesville, FL 32611-36400, USA.

出版信息

Nanomedicine (Lond). 2010 Feb;5(2):233-42. doi: 10.2217/nnm.09.106.

Abstract

AIMS

Fluorescent cerium oxide (ceria) nanoparticles were developed through incorporation of erbium into the lattice. Catalytic properties and luminescent behavior are examined.

MATERIALS & METHODS: Cerium-erbium mixed oxide nanoparticles were synthesized by the reverse micelles route. Purity, size, and composition were characterized. Catalytic properties were measured using a hydrogen peroxide assay, and the luminescence properties were determined by confocal microscopy.

RESULTS

The nanoparticles exhibited enhancement of the catalytic properties with increasing erbium content to 10 mole% in the cerium oxide lattice; and they demonstrated emission at 515 nm and 572.5 nm under 405 nm UV excitation in aqueous conditions.

CONCLUSION

Erbium incorporation into ceria-based nanoparticles were developed, having catalytic properties similar to and better than purely synthesized ceria and luminescent properties under UV irradiation by confocal microscopy.

摘要

目的

通过将铒掺入晶格中,开发出荧光氧化铈(CeO2)纳米粒子。考察了其催化性能和发光行为。

材料与方法

采用反胶束法合成铈-铒混合氧化物纳米粒子。对其纯度、粒径和组成进行了表征。通过过氧化氢测定法测量了催化性能,通过共聚焦显微镜测定了发光性能。

结果

纳米粒子表现出随着铒含量在氧化铈晶格中增加到 10 摩尔%,催化性能增强;并且在水相条件下,在 405nmUV 激发下,它们在 515nm 和 572.5nm 处发出荧光。

结论

成功开发了基于铈的纳米粒子掺入铒,其具有与纯合成 CeO2 相似甚至更好的催化性能,并且在共聚焦显微镜下的 UV 照射下具有发光性能。

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