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六价铬在聚乙烯亚胺浸渍的棕榈壳活性炭上的吸附。

Hexavalent chromium adsorption on impregnated palm shell activated carbon with polyethyleneimine.

机构信息

Department of Chemical Engineering, Faculty of Engineering, University of Malaya, 50603 Kuala Lumpur, Malaysia.

出版信息

Bioresour Technol. 2010 Jul;101(14):5098-103. doi: 10.1016/j.biortech.2010.01.135. Epub 2010 Feb 13.

Abstract

Removal of Cr(VI) ions from aqueous solution was investigated using modified palm shell activated carbon. Low Molecular Weight Polyethyleneimine (LMW PEI) was used for impregnation purpose. The maximum amount of LMW PEI adsorbed on activated carbon was determined to be approximately 228.2mg/g carbon. The adsorption experiments were carried out in a batch system using potassium dichromate K(2)Cr(2)O(7) as the source of Cr(VI) in the synthetic waste water and modified palm shell activated carbon as the adsorbent. The effects of pH, concentration of Cr(VI) and PEI loaded on activated carbon were studied. The adsorption data were found to fit well with the Freundlich isotherm model. This modified Palm shell activated carbon showed high adsorption capacity for chromium ions.

摘要

采用改性棕榈壳活性炭去除水溶液中的六价铬离子。采用低分子量聚乙烯亚胺(LMWPEI)进行浸渍。确定改性棕榈壳活性炭上吸附的LMWPEI 的最大量约为 228.2mg/g 炭。吸附实验在间歇系统中进行,以重铬酸钾 K(2)Cr(2)O(7)为合成废水中 Cr(VI)的来源,以改性棕榈壳活性炭为吸附剂。研究了 pH 值、Cr(VI)浓度和负载在活性炭上的 PEI 的影响。吸附数据与 Freundlich 等温线模型拟合良好。这种改性的棕榈壳活性炭对铬离子具有高的吸附能力。

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