Department of Chemistry and Pharmaceutical Sciences, VU University Amsterdam, De Boelelaan 1083, 1081 HV Amsterdam, The Netherlands.
Angew Chem Int Ed Engl. 2010 Mar 15;49(12):2102-13. doi: 10.1002/anie.200905689.
Syntheses, properties, and reactivities of nucleophilic phosphinidene complexes [L(n)M=P-R] are reviewed. Emphasis is placed on the electronic tuning of this emerging class of phosphorus reagents, using different ancillary ligands and coordinatively unsaturated transition-metal moieties. The difference in applicability of the established stable 18-electron and transient 16-electron phosphinidenes is addressed.
综述了亲核膦烯配合物[L(n)M=P-R]的合成、性质和反应性。重点介绍了使用不同的辅助配体和配位不饱和过渡金属片段对这一新兴磷试剂类别的电子调谐。讨论了已建立的稳定 18 电子和瞬态 16 电子膦烯的适用性差异。
