Tucker Matthew J, Kim Yung Sam, Hochstrasser Robin M
Department of Chemistry, University of Pennsylvania, Philadelphia, PA 19104-6323, USA.
Chem Phys Lett. 2009 Feb 24;470(1-3):80-84. doi: 10.1016/j.cplett.2009.01.025.
The vibrations in the OCN stretching region of phenyl cyanate are examined by two-dimensional infrared spectroscopy. In water and THF, these spectra display three diagonal peaks having cross peaks characteristic of anharmonically coupled transitions. The pattern of the spectra is reproduced by coupling of two overtones with the OCN fundamental.
通过二维红外光谱研究了异氰酸苯酯中OCN伸缩区域的振动。在水和四氢呋喃中，这些光谱显示出三个对角峰，其具有非谐耦合跃迁特征的交叉峰。通过两个泛音与OCN基频的耦合再现了光谱的模式。
