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2
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Synthesis, crystal structures and magnetic properties of cyanide- and phenolate-bridged [M(III)NiII]2 tetranuclear complexes (M=Fe and Cr).氰化物和酚盐桥联的[M(III)NiII]2四核配合物（M = Fe和Cr）的合成、晶体结构及磁性
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本文引用的文献

1
The inhibition of mitochondrial cytochrome oxidase by the gases carbon monoxide, nitric oxide, hydrogen cyanide and hydrogen sulfide: chemical mechanism and physiological significance.一氧化碳、一氧化氮、氰化氢和硫化氢对线粒体细胞色素氧化酶的抑制作用：化学机制与生理意义
J Bioenerg Biomembr. 2008 Oct;40(5):533-9. doi: 10.1007/s10863-008-9166-6. Epub 2008 Oct 7.
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Bis(alpha-diimine)iron complexes: electronic structure determination by spectroscopy and broken symmetry density functional theoretical calculations.双（α-二亚胺）铁配合物：通过光谱学和破缺对称性密度泛函理论计算确定电子结构
Inorg Chem. 2008 Jun 2;47(11):4579-90. doi: 10.1021/ic7022693. Epub 2008 Apr 29.
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Monovalent iron in a sulfur-rich environment.富硫环境中的一价铁。
Inorg Chem. 2008 Mar 17;47(6):1889-91. doi: 10.1021/ic7023378. Epub 2008 Feb 15.
4
Carbon dioxide activation at the Ni,Fe-cluster of anaerobic carbon monoxide dehydrogenase.厌氧一氧化碳脱氢酶的镍铁簇上的二氧化碳活化作用
Science. 2007 Nov 30;318(5855):1461-4. doi: 10.1126/science.1148481.
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Nickel and the carbon cycle.镍与碳循环。
J Inorg Biochem. 2007 Nov;101(11-12):1657-66. doi: 10.1016/j.jinorgbio.2007.07.014. Epub 2007 Jul 21.
6
Sulfur ligand substitution at the nickel(II) sites of cubane-type and cubanoid NiFe3S4 clusters relevant to the C-clusters of carbon monoxide dehydrogenase.与一氧化碳脱氢酶的C簇相关的立方烷型和类立方烷NiFe3S4簇的镍（II）位点上的硫配体取代。
Inorg Chem. 2007 Apr 2;46(7):2691-9. doi: 10.1021/ic062362z. Epub 2007 Mar 9.
7
The vibrational spectra of the cyanide ligand revisited. Bridging cyanides.氰化物配体的振动光谱再探讨。桥连氰化物。
Inorg Chem. 2007 Apr 2;46(7):2409-16. doi: 10.1021/ic0610482. Epub 2007 Mar 2.
8
Mono{hydrotris(mercaptoimidazolyl)borato} complexes of manganese(II), iron(II), cobalt(II), and nickel(II) halides.锰（II）、铁（II）、钴（II）和镍（II）卤化物的单{氢三（巯基咪唑基）硼酸盐}配合物
Inorg Chem. 2006 Nov 27;45(24):9914-25. doi: 10.1021/ic0610132.
9
Electronic structure of four-coordinate C3v nickel(II) scorpionate complexes: investigation by high-frequency and -field electron paramagnetic resonance and electronic absorption spectroscopies.四配位C3v型镍（II）螯形配合物的电子结构：通过高频和高场电子顺磁共振及电子吸收光谱进行研究
Inorg Chem. 2006 Oct 30;45(22):8930-41. doi: 10.1021/ic060843c.
10
The vibrational spectra of the cyanide ligand revisited: terminal cyanides.氰化物配体的振动光谱再探讨：端基氰化物
Inorg Chem. 2006 Jun 26;45(13):4928-37. doi: 10.1021/ic0514041.

一系列氰基桥联双核配合物。

A Series of Cyanide-Bridged Binuclear Complexes.

作者信息

Mock Michael T, Kieber-Emmons Matthew T, Popescu Codrina V, Gasda Patrick, Yap Glenn P A, Riordan Charles G

机构信息

Department of Chemistry and Biochemistry University of Delaware, Newark, Delaware 19716.

出版信息

Inorganica Chim Acta. 2009 Sep 15;362(12):4553-4562. doi: 10.1016/j.ica.2009.05.042.

DOI:10.1016/j.ica.2009.05.042
PMID:20161111
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2739667/
Abstract

A series of cyanide-bridged binuclear complexes, ('S(3)')Ni-CN-M[Tp(tBu)] ('S(3)' = bis(2-mercaptophenyl)sulfide, Tp(tBu) = hydrotris(3-tert-butylpyrazolyl)borate, M = Fe (2-Fe), Co (2-Co), Ni (2-Ni), Zn (2-Zn)) was prepared by the coupling of K[('S(3)')Ni(CN)] with [Tp(tBu)]MX. The isostructural series of complexes was structurally and spectroscopically characterized. A similar coupling strategy was used to synthesize the anionic copper(I) analogue, Et4N{('S3')Ni-CN-Cu[Tp(tBu)]}, 2-Cu.An alternative synthesis was devised for the preparation of the linkages isomers of 2-Zn, i.e. of cyanide-bridged linkage isomers. X-ray diffraction, (13)C NMR and IR spectral studies established that isomerization to the more stable Ni-CN-Zn isomer occurs. DFT computational results buttressed the experimental observations indicating that the cyanide-bridged isomer is ca. 5 kcal/mol more stable than its linkage isomer.

摘要

通过将K[('S(3)')Ni(CN)]与[Tp(tBu)]MX偶联，制备了一系列氰基桥联双核配合物('S(3)')Ni-CN-M[Tp(tBu)]（'S(3)' = 双(2-巯基苯基)硫醚，Tp(tBu) = 氢三(3-叔丁基吡唑基)硼酸酯，M = Fe (2-Fe)、Co (2-Co)、Ni (2-Ni)、Zn (2-Zn)）。对该等结构系列的配合物进行了结构和光谱表征。采用类似的偶联策略合成了阴离子型铜(I)类似物Et4N{('S3')Ni-CN-Cu[Tp(tBu)]}，即2-Cu。设计了另一种合成方法来制备2-Zn的键合异构体，即氰基桥联键合异构体。X射线衍射、(13)C NMR和红外光谱研究表明，会发生异构化生成更稳定的Ni-CN-Zn异构体。密度泛函理论计算结果支持了实验观察结果，表明氰基桥联异构体比其键合异构体稳定约5千卡/摩尔。