Materials Research Laboratory, University of California, Santa Barbara, CA 93106-5121, USA.
Chem Commun (Camb). 2010 Mar 7;46(9):1556-8. doi: 10.1039/b921598k. Epub 2010 Jan 28.
A simple synthetic strategy has been developed for accessing internally functionalized dendrimers. The key feature of this approach is the use of two orthogonal and efficient reactions--'epoxy-amine' and 'thiol-ene' coupling--for rapid growth of the dendritic scaffold. This sequence of reactions allows for the introduction of reactive hydroxyl groups at each dendritic layer.
现已开发出一种简单的合成策略，可用于获取内部官能化的树突状聚合物。该方法的关键特点是使用两种正交且高效的反应——“环氧化合物-胺”和“硫醇-烯”偶联——来快速生长树枝状支架。该反应序列允许在每个树枝状层中引入反应性羟基。
