(m-氟苯胺基)(二环己烷[18]冠-6)[Ni(dmit)2]中[Ni(dmit)2]-阴离子的铁磁耦合。
Ferromagnetic coupling of [Ni(dmit)2]- anions in (m-fluoroanilinium)(dicyclohexano[18]crown-6)[Ni(dmit)2].
机构信息
Research Institute for Electronic Science, Hokkaido University, Sapporo, 001-0020, Japan.
出版信息
Dalton Trans. 2010 Mar 7;39(9):2191-3. doi: 10.1039/b920600k. Epub 2010 Jan 15.
DOI:10.1039/b920600k
PMID:20162189
Abstract
Ferromagnetic coupling of the Ni(dmit)(2) anion layer through lateral sulfur-sulfur interactions along the short-axis of the anion was achieved using the flexible supramolecular cation of (m-fluoroanilinium(+))(meso-dicyclohexano[18]crown-6).
摘要
通过柔性超分子阳离子 (m-氟苯胺 (+))(meso-二环己烷[18]冠-6)，实现了 Ni(dmit)(2) 阴离子层沿阴离子短轴通过横向硫-硫相互作用的铁磁耦合。
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