采用杯芳烃作为组织支架的图案化金属多面体：基于 Ir4 的团簇组装。
Patterned metal polyhedra using calixarenes as organizational scaffolds: Ir4-based cluster assemblies.
机构信息
Department of Chemical Engineering, University of California, Berkeley, CA 94720-1462, USA.
出版信息
Dalton Trans. 2010 Mar 7;39(9):2194-7. doi: 10.1039/b922300b. Epub 2010 Jan 14.
DOI:10.1039/b922300b
PMID:20162190
Abstract
Isolated and patterned assemblies of Ir(4)-based metal polyhedra are described, in which a coordinated calixarene phosphine ligand enforces the desired cluster organization. The compounds are characterized by single-crystal X-ray diffraction and infrared spectroscopy.
摘要
本文描述了孤立且具有图案的 Ir(4)-基金属多面体组装体，其中一个配位的杯芳烃膦配体强制形成所需的簇状结构。这些化合物通过单晶 X 射线衍射和红外光谱进行了表征。
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