Institute of Inorganic Chemistry, Slovak Technical University (FCHPT), SK-812 37, Bratislava, Slovakia.
Dalton Trans. 2010 Mar 7;39(9):2198-200. doi: 10.1039/b919120h. Epub 2010 Jan 12.
The complex [Fe(II){(CN)Fe(III)L(5)}(6)]Cl(2) consists of a mixed-valence heptanuclear cyanide-bridged unit formed of a Schiff-base pentadentate ligand L(5) and it shows a spin crossover of the peripheral Fe(III) centres.
该配合物 [Fe(II){(CN)Fe(III)L(5)}(6)]Cl(2) 由一个混合价的七核氰桥单元组成,该单元由一个希夫碱五齿配体 L(5) 构成,并且其外围的 Fe(III) 中心表现出自旋交叉现象。